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Isabelle DANIEL

par Henri-Claude NATAF, Xavier ROBERT - 5 août 2013 ( dernière mise à jour : 8 novembre 2013 )

Pour télécharger la vidéo (clic droit —> Enregistrer sous) : http://cyan1.grenet.fr/podcastmedia/les-podcasts-de-lujf/20131107_conference-a-isterre_isabelle-daniel_solubilite-des-carbonates-en-zone-de-subduction.m4v

  • Solubilité des carbonates en zone de subduction

  • Isabelle DANIEL, Laboratoire de Géologie de Lyon
  • Carbonate minerals may be recycled into the mantle or dissolved in fluids in subduction zones. However, the evolution of carbonate minerals in equilibrium with aqueous fluids as well as the nature of the chemical species of dissolved carbon in the deep crust and mantle at high PT conditions are still unknown. We report an integrated experimental and theoretical study of the equilibration of carbonate minerals with aqueous solutions at the pressure and temperature characteristics of subduction zones. The fluid speciation was studied using in situ Raman spectroscopy in an externally heated diamond anvil cell. Solubilities were measured using X-ray fluorescence at the ESRF. At equilibrium with the carbonate crystal, the Raman data show that bicarbonate is the most abundant species in low-pressure fluids whereas carbonate becomes progressively dominant at higher pressure. The relative amounts of dissolved carbonate and bicarbonate were estimated from the areas of the ν1 and ν5 symmetric stretching Raman modes of the carbonate and bicarbonate ions, respectively after correction from their Raman cross-sections. The Raman data were used to constrain a theoretical thermodynamic model of the fluid speciation in equilibrium with carbonate minerals. Revised thermodynamic properties of aqueous CO2 and HCO3-, data for the aqueous CaHCO3+ complex from 4 to 90°C, and estimated dielectric constants of water, enabled an equation of state characterization of the standard Gibbs free energy of CaHCO3+ at the conditions of the Raman study. At 300-400°C, the Raman speciation results were used to constrain equilibrium constants involving the carbonate ion. The results indicate that CO2 is a minor species in fluids in equilibrium with aragonite at 300-500°C and P > 1 GPa. Instead, the CaHCO3+ species becomes important at high pressures until carbonate ion including the integration of the CaCO30 complex become the dominant C-species. The model is validated against independent measurements of the solubility.
  • 7 novembre 2013, 11 h 00

    Salle de conférence, 1er étage

  • OSUG-C, 1381 rue de la piscine, Campus Universitaire
  • Arrêt Tram B/C Bibliothèques universitaires
  • Version PDF

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